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Crystallization of polymers. Volume 1, Equilibrium concepts - Original PDF
Crystallization of polymers. Volume 1, Equilibrium concepts - Original PDF
نویسندگان: Mandelkern Leo, NetLibrary Inc خلاصه: Polymers of high molecular weight have now been accepted as respectable members of the molecular community. This situation was not always true.(1) It is now recognized, however, that polymer molecules possess the unique structural feature of being composed of a very large number of chain units that are covalently linked together. This property is common to all macromolecules despite their diverse origin, their widely differing chemical and stereochemical structures and uses and function. It is, therefore, possible to study this class of substances from a unified point of view that encompasses the relatively simpler polymers prepared in the laboratory, as well as the more complex ones of nature. The characteristic thermodynamic, hydrodynamic, physical, and mechanical properties possessed by high polymeric substances can be explained, in the main, by their covalent structure and the attendant large size of the individual molecules.

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