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Ebook details:
عنوان: Introduction to Reticular Chemistry Metal-Organic Frameworks and Covalent Organic Frameworks (9783527345021)
نویسنده: Omar M. Yaghi, Markus J. Kalmutzki, Christian S. Diercks
ناشر: Wiley-VCH; 1 edition (May 6, 2019)
زبان: English
شابک: 3527345027, 978-3527345021
حجم: 29 Mb
فرمت: True Pdf

Cover; Title Page; Copyright; Contents; About the Companion Website; Foreword; Acknowledgment; Introduction; Abbreviations; Part I Metal‐Organic Frameworks; Chapter 1 Emergence of Metal‐Organic Frameworks; 1.1 Introduction; 1.2 Early Examples of Coordination Solids; 1.3 Werner Complexes; 1.4 Hofmann Clathrates; 1.5 Coordination Networks; 1.6 Coordination Networks with Charged Linkers; 1.7 Introduction of Secondary Building Units and Permanent Porosity; 1.8 Extending MOF Chemistry to 3D Structures; 1.8.1 Targeted Synthesis of MOF‐5; 1.8.2 Structure of MOF‐5 1.8.3 Stability of Framework Structures1.8.4 Activation of MOF‐5; 1.8.5 Permanent Porosity of MOF‐5; 1.8.6 Architectural Stability of MOF‐5; 1.9 Summary; References; Chapter 2 Determination and Design of Porosity; 2.1 Introduction; 2.2 Porosity in Crystalline Solids; 2.3 Theory of Gas Adsorption; 2.3.1 Terms and Definitions; 2.3.2 Physisorption and Chemisorption; 2.3.3 Gas Adsorption Isotherms; 2.3.4 Models Describing Gas Adsorption in Porous Solids; 2.3.4.1 Langmuir Model; 2.3.4.2 Brunauer-Emmett-Teller (BET) Model; 2.3.5 Gravimetric Versus Volumetric Uptake 2.4 Porosity in Metal‐Organic Frameworks2.4.1 Deliberate Design of Pore Metrics; 2.4.2 Ultrahigh Surface Area; 2.5 Summary; References; Chapter 3 Building Units of MOFs; 3.1 Introduction; 3.2 Organic Linkers; 3.2.1 Synthetic Methods for Linker Design; 3.2.2 Linker Geometries; 3.2.2.1 Two Points of Extension; 3.2.2.2 Three Points of Extension; 3.2.2.3 Four Points of Extension; 3.2.2.4 Five Points of Extension; 3.2.2.5 Six Points of Extension; 3.2.2.6 Eight Points of Extension; 3.3 Secondary Building Units; 3.4 Synthetic Routes to Crystalline MOFs; 3.4.1 Synthesis of MOFs from Divalent Metals 3.4.2 Synthesis of MOFs from Trivalent Metals3.4.2.1 Trivalent Group 3 Elements; 3.4.2.2 Trivalent Transition Metals; 3.4.3 Synthesis of MOFs from Tetravalent Metals; 3.5 Activation of MOFs; 3.6 Summary; References; Chapter 4 Binary Metal‐Organic Frameworks; 4.1 Introduction; 4.2 MOFs Built from 3‐, 4‐, and 6‐Connected SBUs; 4.2.1 3‐Connected (3‐c) SBUs; 4.2.2 4‐Connected (4‐c) SBUs; 4.2.3 6‐Connected (6‐c) SBUs; 4.3 MOFs Built from 7‐, 8‐, 10‐, and 12‐Connected SBUs; 4.3.1 7‐Connected (7‐c) SBUs; 4.3.2 8‐Connected (8‐c) SBUs; 4.3.3 10‐Connected (10‐c) SBUs; 4.3.4 12‐Connected (12‐c) SBUs 4.4 MOFs Built from Infinite Rod SBUs4.5 Summary; References; Chapter 5 Complexity and Heterogeneity in MOFs; 5.1 Introduction; 5.2 Complexity in Frameworks; 5.2.1 Mixed‐Metal MOFs; 5.2.1.1 Linker De‐symmetrization; 5.2.1.2 Linkers with Chemically Distinct Binding Groups; 5.2.2 Mixed‐Linker MOFs; 5.2.3 The TBU Approach; 5.2.3.1 Linking TBUs Through Additional SBUs; 5.2.3.2 Linking TBUs Through Organic Linkers; 5.3 Heterogeneity in Frameworks; 5.3.1 Multi‐Linker MTV‐MOFs; 5.3.2 Multi‐Metal MTV‐MOFs; 5.3.3 Disordered Vacancies; 5.4 Summary; References; Chapter 6 Functionalization of MOFs

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